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To make the dough: Place the softened butter in a large mixing bowl. Pour the warm water over the butter, then add the buttermilk, yeast, sugar, salt, and 4 cups (480g) of the flour. Mix until a soft dough forms.
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Knead the dough for 6 to 8 minutes, adding more flour from the remaining 1/2 cup (60g) as needed to form a dough that's soft but not sticky. Cover the dough and let it rise for 45 minutes, or until doubled.
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To make the topping: Generously coat the inside of a 9" x 13" pan with the softened butter. Sprinkle the brown sugar and salt over the butter, then drizzle with honey or syrup.
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To make the filling: Combine the orange zest with the butter. Stir the cinnamon into the brown sugar.
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To assemble: On a lightly floured work surface, roll the dough into a 10" x 16" rectangle. Spread the orange butter over the dough, leaving 1/2" on one of the long edges uncovered. Sprinkle the brown sugar mixture and nuts over the butter. Roll the dough up toward the uncovered edge (the long way), pinching to seal.
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Cut the log into 12 rolls, and lay each one cut-side up in the prepared pan. Cover and let rise for 30 minutes, while you preheat the oven to 400°F.
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Bake the rolls for 20 to 23 minutes, until the tops are evenly golden brown. Remove them from the oven, and let rest for 3 minutes before inverting the pan over a serving platter. Remove the pan, and if needed, use a spatula to scrape out any remaining butter and sugar mixture, spreading it back onto the rolls before serving.
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Storage information: Store leftover Orange Sticky Rolls, well wrapped, at room temperature for several days. Reheat before serving. Freeze for longer storage.